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Acetylene, The Principles Of Its Generation And Use by F. H. Leeds
Book, page 51 / 445


jacketed decomposing vessel, might be free from the trouble of
overheating. Nevertheless it will be seen in Chapter VI. that the use of
copper is not permissible for such purposes, its advantages as a good
conductor of heat being neutralised by its more important defects.

When suitable precautions are not taken to remove the heat liberated in
an acetylene apparatus, the temperature of the calcium carbide
occasionally rises to a remarkable degree. Investigating this point, Caro
has studied the phenomena of heat production in a "dipping" generator--
_i.e._, an apparatus in which a cage of carbide is alternately
immersed in and lifted out of a vessel containing water. Using a
generator designed to supply five burners, he has found a maximum
recording thermometer placed in the gas space of the apparatus to give
readings generally between 60 deg. and 100 deg. C.; but in two tests out
of ten he obtained temperatures of about 160 deg. C. To determine the
actual temperature of the calcium carbide itself, he scattered amongst the
carbide charge fragments of different fusible metallic alloys which were
known to melt or soften at certain different temperatures. In all his ten
tests the alloys melting at 120 deg. C. were fused completely; in two tests
other alloys melting at 216 deg. and 240 deg. C. showed signs of fusion;
and in one test an alloy melting at 280 deg. C. began to soften. Working
with an experimental apparatus constructed on the "dripping" principle--
_i.e._, a generator in which water is allowed to fall in single
drops or as a fine stream upon a mass of carbide--with the deliberate
object of ascertaining the highest temperatures capable of production
when calcium carbide is decomposed in this particular fashion, and
employing for the measurement of the heat a Le Chatelier thermo-couple,
with its sensitive wires lying among the carbide lumps, Lewes has
observed a maximum temperature of 674 deg. C. to be reached in 19 minutes
when water was dripped upon 227 grammes of carbide at a speed of about 8
grammes per minute. In other experiments he used a laboratory apparatus
designed upon the "dipping" principle, and found maximum temperatures, in
four different trials, of 703 deg., 734 deg., 754 deg., and 807 deg. C.,
which were reached in periods of time ranging from 12 to 17 minutes. Even
allowing for the greater delicacy of the instrument adopted by Lewes for
measuring the temperature in comparison with the device employed by Caro,
there still remains an astonishing difference between Caro's maximum of
280 deg. and Lewes' maximum of 807 deg. C. The explanation of this
discrepancy is to be inferred from what has just been said. The generator
used by Caro was properly made of metal, was quite small in size, was

 
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