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Acetylene, The Principles Of Its Generation And Use by F. H. Leeds
Book, page 331 / 445


recovered as a solid mass or as a cream of lime practically pure white in
colour. Sometimes, however, as explained in Chapter II., the lime sludge
is of a bluish grey tint, even in cases where the carbide decomposed was
of good quality and there was no overheating in the generator. Such
discoloration is of little moment for most of the uses to which the
sludge may be put. The residue withdrawn from a carbide-to-water
generator is usually quite fluid; but when allowed to rest in a suitable
pit or tank, it settles down to a semi-solid or pasty mass which contains
on a rough average 47 per cent. of water and 53 per cent. of solid
matter, the amount of lime present, calculated as calcium oxide, being
about 40 per cent. Since 64 parts by weight of pure calcium carbide yield
74 parts of dry calcium hydroxide, it may be said that 1 part of ordinary
commercial carbide should yield approximately 1.1 parts of dry residue,
or 2.1 parts of a sludge containing 47 per cent. of moisture; and sludge
of this character has been stated by Vogel to weigh about 22.5 cwt. per
cubic yard.

Experience has shown that those pasty carbide residues can be employed
very satisfactorily, and to the best advantage from the maker's point of
view, by builders and decorators for the preparation of ordinary mortar
or lime-wash. The mortar made from acetylene lime has been found equal in
strength and other properties to mortar compounded from fresh slaked
lime; while the distemper prepared by diluting the sludge has been used
most successfully in all places where a lime-wash is required,
_e.g._, on fruit-trees, on cattle-pens, farm-buildings, factories,
and the "offices" of a residence. Many of the village installations
abroad sell their sludge to builders for the above-mentioned purposes at
such a price that their revenue accounts are materially benefited by the
additional income. The sludge is also found serviceable for softening the
feed-water of steam boilers by the common liming process; although it has
been stated that the material contains certain impurities--notably "fatty
matter"--which becomes hydrolysed by the steam, yielding fatty acids that
act corrosively upon the boiler-plates. This assertion would appear to
require substantiation, but a patent has been taken out for a process of
drying the sludge at a temperature of 150 deg. to 200 deg. C. in order to
remove the harmful matter by the action of the steam evolved. So purified,
it is claimed, the lime becomes fit for treating any hard potable or
boiler-feed water. It is very doubtful, however, whether the intrinsic value
of acetylene lime is such in comparison with the price of fresh lime that,
with whatever object in view, it would bear the cost of any method of

 
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