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Acetylene, The Principles Of Its Generation And Use by F. H. Leeds
Book, page 311 / 445


a cylinder of known capacity containing (1) gaseous acetylene compressed
to 10 atmospheres, or (2) containing the solution at the same pressure,
if an explosion were to occur, in case (1) the whole contents would
participate in the decomposition, whereas in case (2), as mentioned
already, only the small quantity of gaseous acetylene above the solution
would be dissociated.

It is manifest that of the three varieties of compressed acetylene now
under consideration, the solution in acetone is the only one fit for
general employment; but it exhibits the grave defects (_a_) that the
pressure under which it is prepared must be so small that the pressure in
the cylinders can never approach 20 atmospheres in the hottest weather or
in the hottest situation to which they may be exposed, (_b_) that
the gas does not escape smoothly enough to be convenient from large
vessels unless those vessels are agitated, and (_c_) that the
cylinders must always be used in a certain position with the valve at the
top, lest part of the liquid should run out into the pipes. For these
reasons the simple solution of acetylene in acetone has not become of
industrial importance; but the processes of absorbing either the gas, or
better still its solution in acetone, in porous matter have already
achieved considerable success. Both methods have proved perfectly safe
and trustworthy; but the combination of the acetone process with the
porous matter makes the cylinders smaller per unit volume of acetylene
they contain. Several varieties of solid matter appear to work
satisfactorily, the only essential feature in their composition being
that they shall possess a proper amount of porosity and be perfectly free
from action upon the acetylene or the acetone (if present). Lime does
attack acetone in time, and therefore it is not a suitable ingredient of
the solid substance whenever acetylene is to be compressed in conjunction
with the solvent; so that at present either a light brick earth which has
a specific gravity of 0.5 is employed, or a mixture of charcoal with
certain inorganic salts which has a density of 0.3, and can be introduced
through a small aperture into the cylinder in a semi-fluid condition.
Both materials possess a porosity of 80 per cent., that is to say, when a
cylinder is apparently filled quite full, only 20 per cent, of the space
is really occupied by the solid body, the remaining 80 per cent, being
available for holding the liquid or the compressed gas. If all
comparisons as to degree of explosibility and effects of explosion are
omitted, an analogy may be drawn between liquefied acetylene or its
compressed solution in acetone and nitroglycerin, while the gas or

 
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