Lutetium

Ytterbium - Lutetium - Hafnium Y Lu Lr       Full table
General
Name, Symbol, Number	Lutetium, Lu, 71
Chemical series	Transition metals
Group, Period, Block	3, 6 , d
Density, Hardness	9841 kg/m3, __
Appearance	Silvery white
Atomic properties
Atomic weight	174.967 amu
Atomic radius (calc.)	175 (217) pm
Covalent radius	160 pm
van der Waals radius	no data
Electron configuration	[Xe]4f14 5d1 6s2
e- 's per energy level	2, 8, 18, 32, 9, 2
Oxidation states (Oxide)	3 (weak base)
Crystal structure	hexagonal
Physical properties
State of matter	solid (__)
Melting point	1925 K (3006 °F)
Boiling point	3675 K (6156 °F)
Molar volume	17.78 ×10-6 m3/mol
Heat of vaporization	355.9 kJ/mol
Heat of fusion	18.6 kJ/mol
Vapor pressure	2460 Pa at 1936 K
Velocity of sound	no data
Miscellaneous
Electronegativity	1.27 (Pauling scale)
Specific heat capacity	150 J/(kg*K)
Electrical conductivity	1.85 106/m ohm
Thermal conductivity	16.4 W/(m*K)
1st ionization potential	523.5 kJ/mol
2nd ionization potential	1340 kJ/mol
3rd ionization potential	2022.3 kJ/mol
4th ionization potential	4370 kJ/mol
5th ionization potential	6445 kJ/mol
Most stable isotopes
iso NA half-life DM DE MeV DP 173Lu {syn.} 1.37 y ε 0.671 173Yb 174Lu {syn.} 3.31 y ε 1.374 174Yb 175Lu 97.41% Lutetium is stable with 104 neutrons 176Lu 2.59% 3.78 E10 y β- 1.193 176Hf
SI units & STP are used except where noted.

Notable characteristics and applications

Lutetium is a silvery white corrosion-resistant trivalent metal that is relatively stable in air and is the heaviest and hardest of the rare earth elements.

This element is very expensive to obtain in useful quantities and therefore it has very few commercial uses. However, stable lutetium can be used as catalysts in petroleum cracking in refineries and can also be used in alkylation, hydrogenation, and polymerization applications.

History

Lutetium (Latin Lutetia meaning Paris) was independently discovered in 1907 by French scientist Georges Urbain and Austrian mineralogist Baron Carol Auer von Welsbach. Both men found lutetium as an impurity in the mineral ytterbia which was thought by Swiss chemist Jean Charles Galissard de Marignac (and most others) to consist entirely of the element ytterbium.

The separation of lutetium from Marignac's ytterbium was first described by Urbain and the naming honor therefore went to him. He chose the names neoytterbium (new ytterbium) and lutecium for the new element but neoytterbium was eventually reverted back to ytterbium and in 1949 the spelling of element 71 was changed to lutetium.

Welsbach proposed the names cassiopium for element 71 (after the constellation Cassiopeia) and albebaranium for for the new name of ytterbium but these naming proposals where rejected (although many German scientists still call element 71 cassiopium).

Occurrence

Found with almost all other rare-earth metals but never by itself, lutetium is very difficult to separate from other elements and is the least abundant of all naturally-occurring elements.

The principal commercially viable ore of lutetium is the mineral monzonite [(Ce, La, etc.)PO₄] which contains 0.003% of the element. Pure lutetium metal has only relatively recently been isolated and is very difficult to prepare (thus it is one of the most rare and expensive of the rare earth metals). It is separated from other rare earth elements by ion exchange (reduction of anhydrous LuCl₃ or LuF₃ by either an alkali metal or alkaline earth metal).

Isotopes

Naturally occurring lutetium is composed of 1 stable isotope Lu-175 (97.41% natural abundance). 33 radioisotopes have been characterized, with the most stable being Lu-176 with a half-life of 3.78 × 10¹⁰ years (2.59% natural abundance), Lu-174 with a half-life of 3.31 years, and Lu-173 with a half-life of 1.37 years. All of the remaining radioactive isotopes have half-lifes that are less than 9 days, and the majority of these have half lifes that are less than a half an hour. This element also has 18 meta states, with the most stable being Lum-177 (t_½ 160.4 days), Lum-174 (t_½ 142 days) and Lum-178 (t_½ 23.1 minutes).

The isotopes of lutetium range in atomic weight from 149.973 amu (Lu-150) to 183.961 amu (Lu-184). The primary decay mode before the most abundant stable isotope, Lu-175, is electron capture (with some alpha and positron emission), and the primary mode after is beta emission. The primary decay products before Lu-175 are element 70 (ytterbium) isotopes and the primary products after are element 72 (hafnium) isotopes.

Compounds

Fluoride: LuF₃, Chloride: LuCl₃, Bromide: LuBr₃, Iodide: LuI₃, Oxide: Lu₂O₃, Sulfide: Lu₂S₃, Telluride: Lu₂Te₃, Nitride: LuN

Precautions

Like other rare-earth metals lutetium is regarded as having a low toxicity rating but it and especially its compounds should be handled with care nonetheless. Metal dust of this element is a fire and explosion hazard. Lutetium plays no biological role in the human body but is thought to help stimulate metabolism.

References

• Guide to the Elements - Revised Edition, Albert Stwertka, (Oxford University Press; 1998) ISBN 0-19-508083-1
• Los Alamos National Laboratory's Chemistry Division: Periodic Table - Lutetium

External links

• WebElements.com - Lutetium (also used as a reference)
• EnvironmentalChemistry.com - Lutetium (also used as a reference)
• It's Elemental - Lutetium

Referenced By